You can run the PowerShell Scirpt below on Exchange 2010 SP3 server to export Mailbox Usage Report to CSV File
#Connect to Exchange - PowerShell ISE - Exchange 2010
. 'C:\Program Files\Microsoft\Exchange Server\V14\bin\RemoteExchange.ps1'
Connect-ExchangeServer -auto
$Results = @() #Declare Array for all results
$Mailboxes = Get-Mailbox -ResultSize Unlimited -RecipientType UserMailbox
#$Mailboxes = Get-Mailbox -identity group2
foreach($Mailbox in $Mailboxes)
{
$UPN = $Mailbox.UserPrincipalName
$MailboxStat = Get-MailboxStatistics $UPN
$Properties = @{
Name = $Mailbox.DisplayName
UPN = $UPN
Database = $mailboxStat.Database
LastLogon = $MailboxStat.lastlogontime
TotalItems = $MailboxStat.ItemCount
TotalItemSize = $MailboxStat.TotalItemSize.Value.ToMB()
DeletedItems = $MailboxStat.TotalDeletedItemSize.Value.ToMB()
}
$Results += New-Object psobject -Property $properties
}
$Results | Export-Csv C:\temp\mailboxreport-20181707.csv -NoTypeInformation
You will get the CSV Report as below